Battery Encyclopedia
Everything you want to know about batteries from A to Z, curated by TWAICE experts.
A form of carbon used as an electrode material in many batteries, known for its electrical conductivity and ability to intercalate lithium ions.
In the context of batteries, heat-transfer coefficients quantify how efficiently heat can be transferred away from the battery cells. High heat-transfer coefficients are desirable to efficiently dissipate heat and maintain optimal operating temperatures, thereby enhancing battery performance and lifespan.
In the context of batteries, it refers to the different equilibrium potentials (difference in voltage between charging and discharging) at the same state of charge. The hysteresis effect can be very pronounced dependent upon the battery chemistry, requiring very accurate estimation or measurement of the terminal voltage.
Energy resources that use inverters to convert DC electricity to AC, enabling integration with the electrical grid.
A condition where cells in a battery pack exhibit varying states of charge, health, or voltage, affecting performance and longevity.
Contains information about the internal state of a battery and is composed of internal resistance and reactance, which are measured under defined conditions such as AC frequency, state of charge, state of health, and temperature.
In the energy sector, integrators refer to systems or companies that combine various energy technologies and services to provide a comprehensive solution. This can include integrating renewable energy sources with traditional power systems, battery storage, and smart grid technologies to improve efficiency, reliability, and sustainability.
Intercalation of ions refers to the process where ions are inserted into the layers of a material without significantly altering its overall structure. This process is commonly seen in materials like graphite or layered metal oxides, where ions, such as lithium ions in the case of lithium-ion batteries, are reversibly inserted between the layers of the host material. The intercalation process is key to the functioning of various electrochemical systems, including rechargeable batteries, as it allows for the storage and release of energy.
Internal resistance in a battery refers to the amount of resistance that the battery's internal components, such as electrodes, electrolyte, and terminals, present to the flow of current within the battery. This resistance causes some of the electrical energy produced by the battery to be converted into heat, reducing the amount of available voltage and current that can be delivered to an external circuit.
An inverter converts direct current (DC) from batteries into alternating current (AC) and vice versa. One use case is to convert direct current from batteries into alternating current for use in homes, businesses, and the grid. Inverters are crucial for integrating battery systems with existing electrical infrastructure
"Inverter imbalance" refers to a condition where the output of an inverter (a device that converts direct current (DC) to alternating current (AC)) is not balanced across its phases. This typically occurs in three-phase inverters, where the voltages or currents in the three output phases (commonly denoted as A, B, and C) are not equal or not 120 degrees out of phase with each other as they should be in a perfectly balanced system.
Iron is a key component of the cathode of lithium iron phosphate (LiFePO₄) batteries, where it forms the cathode material. Lithium iron phosphate (LiFePO₄) is known for its thermal stability, safety, long cycle life, and relatively low cost, although it offers lower energy density compared to other cathode materials like lithium cobalt oxide or NMC (nickel manganese cobalt)
The unit of energy in the International System of Units (SI), defined as the energy transferred when one ampere of current passes through a resistance of one ohm for one second.
A Key Performance Indicator (KPI) in the context of batteries is a measurable value used to evaluate the performance and efficiency of a battery system. KPIs for batteries might include metrics such as energy density, cycle life, charge and discharge rates, efficiency, and capacity retention. These indicators help assess how well a battery performs under specific conditions and guide improvements in battery technology.
LCO is a widely used lithium-ion battery cathode chemistry known for its high energy density and good cycle life. It’s predominantly used in portable electronic devices such as smartphones, laptops, and cameras. It was the initial cell chemistry in the 1990s when Sony commercialized the Li-ion battery.
LFP is a lithium-ion battery cathode chemistry offering high thermal stability, long cycle life, and excellent safety features. It’s commonly used in electric vehicles, grid storage systems, and industrial applications.
This is a type of cathode material used in lithium-ion batteries. It offers benefits like high thermal stability, safety, and a long cycle life, although it typically has a lower energy density compared to other cathode materials like NMC (Nickel Manganese Cobalt Oxide).
LMO is a lithium-ion battery cathode chemistry that provides high power output and good thermal stability. It’s used in power tools, electric bikes, and some electric vehicles.
LTO is a lithium-ion battery anode chemistry known for its extremely fast charging capabilities, long cycle life, and high safety. It’s used in applications that require rapid charging and discharging, such as electric buses and grid storage.
Lithium is a key component in both the cathode and anode of lithium-ion batteries. In the cathode, it is often found in compounds like lithium cobalt oxide (LiCoO₂), lithium iron phosphate (LiFePO₄), and lithium nickel manganese cobalt oxide (NMC). In the anode, lithium can be used in the form of lithium metal or intercalated in graphite. Lithium enhances the battery’s energy density, allowing for longer-lasting, lightweight, and efficient power storage.
Lithium plating is a phenomenon that occurs in lithium-ion batteries when lithium ions are deposited as metallic lithium onto the anode (typically made of graphite) instead of being intercalated or inserted between the anode’s carbon layers.
This usually occurs under specific conditions like fast charging, charging at low temperatures, or when the cell is already at a high state of charge. Over time, this can create dendritic structures that may penetrate the separator, posing a risk of short-circuiting the battery. This not only reduces the battery’s life but also increases safety risks, as internal shorts can lead to thermal runaway and potential fires or explosions.
A type of rechargeable battery in which lithium ions move from the negative electrode (anode) to the positive electrode (cathode) during discharging and back again during charging .They are commonly used in mobile phones, laptops, electric vehicles, and grid-scale energy storage due to their comparatively high energy density and lightweight characteristics.
LAMne describes the degradation or consumption of the active material within the anode of a battery. For many lithium-ion batteries, graphite is the primary active material in the anode. Its layered structure allows for the intercalation of lithium ions. The loss of active anode material directly impacts the battery's capacity and overall cycle life. As the graphite is consumed, the battery's ability to store energy diminishes, leading to a decrease in its overall performance and efficiency.
LAMpe describes the degradation or consumption of the active material within the cathode of a battery. Several materials are used as active cathode materials in lithium-ion batteries. Common examples include Lithium Cobalt Oxide (LCO), Lithium Iron Phosphate (LFP), and Lithium Nickel Manganese Cobalt Oxide (NMC). The loss of active cathode material results in reduced energy storage capacity of the battery. As these materials degrade, the overall energy density of the battery diminishes, leading to shorter usable battery life and decreased performance.
In battery cells, this refers to the disruption of the electrical connection within the cell, which can occur due to various reasons such as physical degradation of electrode materials, breakdown of the conductive network, or mechanical stresses. This loss impedes the efficient flow of electrons, crucial for battery operation, leading to reduced performance, efficiency, and sometimes complete failure of the battery cell.
Refers to the irreversible loss of lithium ions in a battery, which can result from side reactions such as the formation of the solid-electrolyte interphase. This loss leads to a reduction of the overall capacity of a battery.
A machine learning model is an algorithmic structure that, based on input data, makes predictions or decisions, identifying patterns or making decisions with minimal human intervention. These models can range from simple linear regression to complex neural networks. They are trained on a set of data (training dataset) to learn from the properties of the data and then used to make predictions on new, unseen data. Machine learning models have a wide range of applications, including image and speech recognition, medical diagnosis, stock market trading, and battery performance prediction.
Failures in a system or device, such as a battery, that prevent it from operating as intended.
NCA is a high-performance lithium-ion battery cathode chemistry known for its high energy density, long cycle life, and fast charging capabilities. It’s commonly used in electric vehicles, such as Tesla models, and portable electronics.
National Fire Protection Association standards that provide safety guidelines for the installation of stationary energy storage systems. It covers requirements for system design, installation, ventilation, and maintenance, ensuring the safety of both the public and first responders.
NMC is a popular lithium-ion battery cathode chemistry, offering a high energy density, good thermal stability, and relatively low cost. It’s widely used in electric vehicles, portable electronics, and grid storage applications. First NMC cathodes contained the same amount of nickel (Ni), manganese (Mn) and cobalt (Co) and were called NMC111 or NMC333. Recent developments increased the amount of Ni and reduced the Mn and Co content leading to relations such as 8 portions of Ni to 1 portion of Mn and Co, also called NMC811.
NPCC (Northeast Power Coordinating Council) is a regional organization responsible for ensuring the reliability and security of the electric grid in the Northeastern United States and parts of Canada. NPCC oversees the coordination of power system operations, develops and enforces reliability standards, and promotes collaboration among utilities and grid operators within its jurisdiction to maintain a stable and reliable electric grid.
Nickel is primarily used in the cathode of lithium-ion batteries, typically in nickel-rich compounds like lithium nickel manganese cobalt oxide (NMC), nickel-metal hydride (NiMH) and lithium nickel cobalt aluminum oxide (NCA). Nickel improves the battery's energy density, stability, and overall performance, making it suitable for high-capacity and long-lasting energy storage.
Nominal voltage is the average voltage at which a battery operates during its discharge cycle. It is a key parameter for determining the battery's compatibility with devices and applications. For lithium-ion batteries, the nominal voltage typically ranges between 3.3V and 3.8V, depending on the cell chemistry.
The property of a battery that causes its discharge behavior to vary non-linearly with different loads and conditions.
OCV aging refers to the decline or shift in the open circuit voltage of a battery over its lifespan. This change in OCV is due to the irreversible chemical and physical changes within the battery as it ages. Factors contributing to OCV aging include loss of active materials, formation and growth of the solid-electrolyte interface (SEI), and other degradation mechanisms. As the battery ages, its maximum and minimum OCV values can shift, affecting its total usable capacity. A shift in OCV values can make state of charge estimation more challenging, potentially leading to reduced battery performance and lifespan.
A condition where there is a break in the circuit path, preventing current flow.
OCV is the difference of electrical potential across the terminals of a battery when it's not under any load (i.e., when no current flows in or out of the battery). The OCV of a lithium-ion battery is determined under certain conditions such as state of charge (SoC) or temperature and can vary with respect to the specific chemistry of the cell.
These strategies may include managing the charging and discharging cycles to balance performance with battery life, or dynamically adjusting parameters based on real-time usage and vehicle/grid conditions.
These are the boundaries within which a battery or energy system must operate to ensure safety, reliability, and longevity. Operating limits can include maximum and minimum state of charge, voltage levels, temperature ranges, and charge/discharge rates.
Refers to charging a battery beyond its maximum voltage limit. Overcharging can lead to overheating, electrolyte breakdown, and in severe cases, to a thermal runaway.
In the context of battery systems, oversizing refers to the practice of installing a battery with more capacity than what is routinely needed. This is often done to account for future load increases, degradation of the battery over time, or to ensure reliability and uninterrupted power supply in critical applications.
A market mechanism that compensates participants for providing immediate response services to help balance grid frequency.
In battery cells, particle cracking refers to the mechanical degradation of electrode materials, often seen in cathode particles. This can happen due to repeated charging and discharging cycles, leading to a decrease in the mechanical integrity of the particles. This degradation can cause a loss of electrical contact within the electrode, reducing the battery's capacity and efficiency over time.
The Performance Manager from TWAICE is a software tool designed to make it effortless for asset managers to identify and rectify underperforming components within their battery energy storage systems (BESS), providing system transparency and actionable business insights. It offers a comprehensive overview of the system, displaying the number of underperforming issues, their severity levels, exact locations within the BESS, and recommended actions.
The combined physical, chemical, and mechanical processes that lead to the deterioration of battery materials and performance.
A type of battery cell that is housed in a flexible, flat, and rectangular package. The packaging material usually is a laminate of thin metal and plastic layers.
Power refers to the rate at which energy is supplied or consumed by a lithium-ion battery, measured in watts (W). A battery with higher power can deliver more energy in a shorter period, enabling faster charging and discharging rates.
A type of battery cell that comes in a rectangular or square shape, housed in a hard metal or plastic case. Prismatic cells are commonly used in energy storage systems and electric vehicles.
Prussian blue is a deep blue pigment with the chemical formula Fe4[Fe(CN)6]3, and in battery applications, it's used in the form of a compound known as "Prussian blue analogs" or "Prussian blue derivatives." It is used in the cathodes of sodium-ion batteries, where its unique structure provides several advantages. The stability, combined with the cost-effectiveness of the materials, makes Prussian Blue a promising option for large-scale energy storage systems, such as grid storage, where long battery life and low costs are critical. Additionally, while still in development, Prussian Blue-based batteries could eventually find applications in electric vehicles, particularly in lower-cost models.
The efficiency of a battery system calculated by dividing the energy output by the energy input over a complete charge-discharge cycle.
Regulation involves the implementation of laws and guidelines governing the production, usage, and disposal of batteries. These rules ensure safety, environmental protection, and fair market practices. For example, the European Union's Battery Directive mandates specific recycling rates for battery materials and requires manufacturers to comply with labeling and performance standards to reduce environmental impact and enhance consumer safety. In the United States, the Battery Act (Battery Management and Recovery Act) sets forth guidelines for battery recycling and disposal, aiming to minimize environmental hazards and promote the safe handling of batteries throughout their lifecycle.
Relaxation time refers to the period a battery needs to reach a stable voltage and temperature after charging or discharging. Understanding relaxation times is crucial for accurate state of charge and state of health estimations.
In the context of batteries and energy systems, reliability refers to the ability of the system to perform its required functions under expected conditions over a specified period. It's a critical factor in applications like power grids, electric vehicles, and portable electronics.
The remaining energy capacity in a battery, indicating how much more charge can be stored. Knowing the residual capacity is important for managing energy usage, planning recharges, and avoiding unexpected power loss. It also plays a key role in determining the end-of-life of a battery when its capacity falls below a certain threshold of its original capacity.
The duration for which a battery or system can operate on a single charge under specified conditions.
Refers to the range within which the State of health (SoH) of a battery can be expected to lie with a certain confidence. It provides a statistical measure of the uncertainty or variability of the SOH estimation.
The voltage range within which a battery or device can operate safely, without risk of damage or unsafe conditions.
This concept involves repurposing used batteries (often from electric vehicles) for new applications, typically less demanding than their original use. For example, EV batteries that have degraded below an acceptable level for vehicle use might still be suitable for stationary energy storage applications.
Self-discharge is the loss of stored energy in a battery when not in use. All batteries exhibit self-discharge to some extent, but lithium-ion batteries generally have a lower self-discharge rate compared to other storage technologies. Minimizing self-discharge can help prolong battery life and maintain optimal performance.
The separator is a critical component in lithium-ion batteries, providing a physical barrier between the anode and cathode to prevent short circuits while allowing lithium ions to passthrough. Separators are typically made from porous materials like polyethylene or polypropylene.
A charging method for batteries that uses lower current over a longer period, often to preserve battery health and extend lifespan.
The process of estimating the State of Charge of a battery, indicating the current energy level relative to its maximum capacity. Accurate SoC estimation allows for the optimal operation of battery systems, preventing overcharging or deep discharging that can harm battery life. Techniques for SoC estimation range from simple voltage-based methods to more complex algorithms that incorporate multiple variables and historical data.
Sodium layered oxides are a class of materials characterized by their layered crystal structure, where sodium (Na) ions are intercalated between layers of metal oxides. The "layered" aspect refers to the stacking of alternating layers of sodium ions and transition metal oxides, which often results in a two-dimensional structure. Sodium layered oxides are of particular interest in the field of energy storage, particularly for use in sodium-ion batteries, due to their ability to reversibly intercalate and de-intercalate sodium ions during charge and discharge cycles. The properties of these materials, such as capacity, stability, and conductivity, can be tuned by varying the type of transition metal and the amount of sodium in the structure.
These are a type of rechargeable battery that uses sodium ions as the charge carrier. Sodium-ion batteries are attractive due to the abundance and low cost of sodium compared to lithium, making them a potentially more sustainable and cost-effective option for large-scale energy storage.
A layer that forms on the electrode/electrolyte interface (on the anode surface) of a lithium-ion battery during the initial charging cycles. While it helps stabilize the battery's operation, its growth also leads to capacity loss and resistance increase over time.
Solid-state batteries are an emerging technology that replaces the liquid electrolyte and the separator in conventional lithium-ion batteries with a solid electrolyte. They offer increased energy density, enhanced safety due to reduced risk of thermal runaway, and improved cycle life. However, solid-state batteries face challenges related to manufacturing, scalability, and cost. In the ideal case, the use of solid-state electrolytes enables the use of anode-free cell configurations, meaning there is no anode available during the manufacturing process, but it is created each discharge process in the form of a thin metallic lithium layer on the anode current collector.
These are algorithms used in battery management systems (BMS) to estimate important battery parameters that cannot be measured by the BMS, like state of charge and state of health. Kalman filters, for example, use a series of measurements observed over time, containing statistical noise and other inaccuracies, and produce estimates of unknown variables that tend to be more precise than those based on a single measurement alone.
In simple terms, the State of Charge (SoC) provides information on how much charge is still available in the battery. In an ideal case, the SoC can be determined by measuring the charge drawn from and pushed back into the battery. A challenge arises since measurements are not fully precise, meaning the measurement of charge out and charge in might be different, just because sensors are not capable enough to count every change of charge. Also, not every charge which is inserted into the battery will be available later on to leave the battery again, since some processes inside consume charge via side reactions. Hence, the SoC needs to be determined by other means, not only by measuring charge in and out, but also by checking the resulting voltage.
The voltage measured outside at the battery is the difference between the cathode and anode potential. The cathode and anode potential is determined by the amount of lithium ions stored within the material. Therefore, one way would be to use a look-up table to check which voltage level corresponds to the amount of lithium ions stored in the battery electrodes, which then can be used to determine the SoC. However, the voltage itself is also affected by temperature and age of the battery. Other effects such as polarizations make the SoC determination only by voltage readings challenging as well.
It is generally defined as the ratio of the current capacity to the initial capacity. SoH is generally defined with capacities (SOHc). However, SoH can also be defined in terms of resistance increase (SOHr) or it can be based on the available energy compared to the initial energy (SOHe). It is also seen that SoH is sometimes scaled between 0 and 1, where 1 is a new cell and 0 is when the cell reaches the End of Life criteria (e.g. 80% remaining capacity).
SoH is a challenging KPI. Firstly, there is often no attention paid to the right framing of the SoH. Since the value is a result based on the division of two values, we need to ensure that both values are actually comparable. That means, the available capacity needs to be determined under the same conditions as the initial capacity. Concretely that means, that i.e. voltage or State of charge limits need to be the same. Otherwise, the available and initial capacity represent different states and are not comparable.
Secondly, the available capacity, energy or resistance needs to be determined during the everyday operation, which follows dynamic and uncontrolled patterns. Additionally, temperature and the operation history influence the available capacity, energy and resistance but their influence must be compensated to determine the actual available state. Therefore, sophisticated models and algorithms are needed to ensure accurate results even with noisy and uncontrolled field data.
This refers to the calculation of the value below which a certain percentage of observations in a dataset fall. For example, the 50th percentile (median) is the value below which 50% of the observations may be found. Percentile computation is widely used to understand the distribution and tendencies in a dataset, such as understanding the performance benchmarks in battery lifecycles or energy consumption patterns.
An energy storage device that offers high power density and rapid charging/discharging capabilities, complementing or replacing batteries in some applications.
Sustainability in batteries involves creating and managing battery systems in ways that minimize environmental impact and promote long-term ecological balance. This includes using eco-friendly materials, efficient production methods, and effective recycling processes.
A theoretical framework used to understand and predict the forces exerted by swelling of battery components during operation.